Publications

31. Exhaustive Reduction of Esters Enabled by Nickel Catalysis

Prakash, S.; Cook, A.; Zheng, Y.-Z.; Newman, S. G. ChemRxiv 2019, pre-print.

DOI: 10.26434/chemrxiv.9917150.v1

30. Nickel-Catalyzed Domino Heck-Type Reactions using Methyl Esters as Cross-Coupling Electrophiles

Zheng, Y.-L.; Newman, S. G. Angew. Chem. Int. Ed. 2019, in press.

DOI: 10.1002/anie.201911372

29. Overcoming Scope Limitations in Cross-Coupling of Diazo Nucleophiles by Manipulating Catalyst Speciation and Using Flow Diazo Generation

Sullivan, R. J.; Freure, G. P. R.; Newman, S. G. ACS Catal. 2019, 9, 5263.

DOI: 10.1021/acscatal.9b01180

Highlighted in Synfacts

28. Ketone Synthesis by a Nickel-Catalyzed Dehydrogenative Cross-Coupling of Primary Alcohols

Verheyen, T.; Turnhout, L. v.; Vandavasi, J. K.; De Borggraeve, W. M.; Isbrandt, E. S.; Newman, S. G. J. Am. Chem. Soc. 2019, 141, 6869.

DOI: 10.1021/jacs.9b03280

27. Methyl Esters as Cross-Coupling Electrophiles: Direct Synthesis of Amide Bonds

Zheng, Y.-L.; Newman, S. G. ACS Catal. 2019, 9, 4426.

DOI: 10.1021/acscatal.9b00884

26. High Throughput Strategies for the Discovery and Optimization of Catalytic Reactions

Isbrandt, E. S.; Sullivan, R. J.; Newman, S. G. Angew. Chem. Int. Ed. 2019, 58, 7180.

DOI: 10.1002/anie.201812534

25. Nickel-Catalyzed Amide Bond Formation from Methyl Esters

Ben Halima, T.; Masson-Makdissi, J.; Newman, S. G. Angew. Chem. Int. Ed. 2018, 57, 12925.

DOI: 10.1002/anie.201808560

24. Flow-Assisted Synthesis of Heterocycles at High Temperatures

Sullivan, J.; Newman, S. in Flow Chemistry for the Synthesis of Heterocycles. K. Sharma & E. Van der Eycken, Eds. Springer 2018.

DOI: 10.1007/7081_2018_18

23. Switchable Selectivity in the Pd-Catalyzed Alkylative Cross-Coupling of Esters

Masson-Makdissi, J.; Vandavasi, J. K.; Newman, S. G. Org. Lett. 2018, 20, 4094.

DOI: 10.1021/acs.orglett.8b01646

22. A High-Throughput Approach to Discovery: Heck-Type Reactivity with Aldehydes

Vandavasi, J. K.; Newman, S. G. Synlett. 2018, 29, 2081.

DOI: 10.1055/s-0037-1610161

Invited Synpacts article

Highlighted in OPRD

21. Overcoming Solid Handling Issues in Continuous Flow Substitution Reactions through Ionic Liquid Formation

Kashani, S. K.; Sullivan, R. J.; Andersen, M.; Newman, S. G. Green Chem. 2018, 20, 1748.

DOI: 10.1039/C8GC00618K

20. Chiral Auxiliary Recycling in Continuous Flow: Automated Recovery and Reuse of Oppolzer’s Sultam

Sullivan, R. J.; Newman, S. G. Chem. Sci. 2018, 9, 2130.

DOI: 10.1039/C7SC05192A

Highlighted in OPRD

19. A Nickel-Catalyzed Carbonyl-Heck Reaction

Vandavasi, J. K.; Hua, X.; Ben Halima, H.; Newman, S. G. Angew. Chem. Int. Ed. 2017, 56, 15441.

DOI: 10.1002/anie.201710241

18. Catalytic Deuteration of Aldehydes with D2O

Isbrandt, E. S.; Vandavasi, J. K.; Zhang, W.; Jamshidi, M. P.; Newman, S. G. Synlett 2017, 28, 2851.

DOI: 10.1055/s-0036-1588540

Invited contribution in honor of Prof. Snieckus

17. A Cross-Coupling Approach to Amide Bond Formation from Esters

Ben Halima, T.; Vanadavasi, J. K.; Shkoor, M.; Newman, S. G. ACS Catalysis 2017, 7, 2176.

DOI: 10.1021/acscatal.7b00245

16. Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Esters

Ben Halima, T.; Zhang, W.; Yalaoui, I.; Hong, X.; Yang, Y.-F.; Houk, K. N.; Newman, S. G. J. Am. Chem. Soc. 2017139, 1311.

DOI: 10.1021/jacs.6b12329

Highlighted in Synfacts

Highlighted in Organic Chemistry Frontiers

15. Inherent Vs Apparent Chemoselectivity in the Kumada-Corriu Cross-Coupling Reaction

Hua, X.; Masson-Makdissi, J.; Sullivan, R. J.; Newman, S. G. Org. Lett. 2016, 18, 5312.

DOI: 10.1021/acs.orglett.6b02631

Highlighted in Synfacts

14. Continuous Thermal Oxidation of Alkenes with Nitrous Oxide in a Packed Bed Reactor

Newman, S. G.; Lee, K.; Cai, J.; Yang, L.; Green, W. H.; Jensen, K. F. Ind. Eng. Chem. Res. 2015, 54, 4166.

DOI: 10.1039/C3GC41942H

13. Pd(0)-Catalyzed Carboiodination: Early Developments and Recent Advances

Petrone, D. A.; Le, C. M.; Newman, S. G.; Lautens, M. RSC Catalysis Series 21. New Trends in Cross-Coupling: Theory and Applications. 2014, 276.

DOI: 10.1039/9781782620259-00276

12. Tools for Chemical Synthesis in Microsystems

Jensen, K. F.; Reizman, B. J.; Newman, S. G. Lab Chip 2014, 14, 3206.

DOI: 10.1039/C3GC41942H

11. Rapid Wolff–Kishner Reductions in a Silicon Carbide Microreactor

Newman, S. G.; Gu, L.; Lesniak, C.; Victor, G.; Meschke, F.; Abahmane, L.; Jensen, K. F. Green Chem. 2014, 16, 176.

DOI: 10.1039/C3GC41942H

10. The Role of Flow in Green Chemistry and Engineering

Newman, S. G.; Jensen, K. F. Green Chem. 2013, 15, 1456.

DOI: 10.1039/C3GC40374B

9. Enantioselective Rh-Catalyzed Domino Transformations of Alkynylcyclohexadienones with Organoboron Reagents

Keilitz, J.; Newman, S. G.; Lautens, M. Enantioselective Rh-Catalyzed Domino Transformations of Alkynylcyclohexadienones with Organoboron Reagents. Org. Lett. 2013, 15, 1148.

DOI: 10.1021/ol400363f

8. Theoretical Study of Pd(0)-Catalyzed Carbohalogenation of Alkenes: Mechanism and Origins of Reactivities and Selectivities in Alkyl Halide Reductive Elimination from Pd(II) Species

Lan, Y.; Liu, P.; Newman, S. G.; Lautens, M.; Houk, K. N. Chem. Sci. 2012, 3, 1987.

DOI: 10.1039/C2SC20103H

7. Palladium-Catalyzed Carbohalogenation: Bromide to Iodide Exchange and Domino Processes

Newman, S. G.; Howell, J. M.; Nicolaus, N.; Lautens, J. Am. Chem. Soc. 2011, 133, 14916.

DOI: 10.1021/ja206099t

6. Palladium-Catalyzed Carboiodination of Alkenes: Carbon-Carbon Bond Formation with Retention of Reactive Functionality

Newman, S. G.; Lautens, M. J. Am. Chem. Soc. 2011, 133, 1778.

DOI: 10.1021/ja110377q

5. The Use of Bromotrichloromethane in Chlorination Reactions

Newman, S. G.; Bryan, C. S.; Perez, D.; Lautens, M. Synthesis 2011, 342.

DOI: 10.1055/s-0030-1258368

4. The Role of Reversible Oxidative Addition in Selective Palladium(0)-Catalyzed Intramolecular
Cross-Couplings of Polyhalogenated Substrates: Synthesis of Brominated Indoles

Newman, S. G.; Lautens, M. J. Am. Chem. Soc. 2010, 132, 11416.

DOI: 10.1021/ja1052335

3. Intramolecular Cross-Coupling of gem-Dibromoolefins: a Mild Approach to 2-Bromo Benzofused Heterocycles

Newman, S. G.; Aureggi, V.; Bryan, C. S.; Lautens, M. Chem. Commun. 2009, 5236.

DOI: 10.1039/B912093A

2. Boron-Catalyzed Direct Aldol Reactions of Pyruvic Acids

Lee, D.; Newman, S. G.; Taylor, M.S. Org. Lett. 2009, 11, 5486.

DOI: 10.1021/ol902322r

1. Factors Controlling Extremely Strong AAA-DDD Triply Hydrogen-Bonded Complexes

Newman, S. G.; Taylor, A.; Boyd, R. J. Chem. Phys. Lett. 2008, 450, 210.

DOI: 10.1016/j.cplett.2007.11.018